Research

Electrolysis is the electrochemical process of water splitting and is the key method of green hydrogen production.

Our water electrolysis research focuses on a number of different aspects, including:

• Synthesis of new, highly active IrOx and doped IrOx catalysts.
• Synthesis of non-precious metal hydrogen evolution (HER) catalysts.
• Ultra-low loading, high mass transport, floating electrode testing of oxygen evolution and hydrogen evolution catalysts.
• Anion exchange membrane (AEM) water electrolysis.
• Polymer electrolyte membrane (PEM) water electrolysis to produce green hydrogen with the co-production of a second valuable chemical such as ozone or hydrogen peroxide.

Redox flow batteries are promising candidates for large scale energy storage due to their versatile architectural design. They consist of an electrochemical cell, fed by external electrolyte storage tanks.

We develop new chemistries and battery components devoted to reducing RFB capital costs and environmental footprint. This research spans a wide range of electrolyte-electrolyte, electrolyte-gas, inorganic and organic chemistries.

Work carried out in this area (utilsing H₂-Mn chemistry, in the form of a regenerative fuel cell) led to the spin out of RFC Power - who are perfecting, scaling and marketing this technology for large scale energy storage applications. We continue to collaborate with RFC, to develope this further.

The concept of electrochemical hydrogen compression is reasonably straightforward – a device, which requires no moving parts, combines both purification and compression in a single electrochemical process. The system, which is not dissimilar to other electrochemical devices, is supplied with an impure and/or lower pressure hydrogen gas stream at the anode, where the gas is oxidised at a catalyst surface. The resulting protons are driven across a proton-specific exchange membrane (PEM) to the cathode, where they are reduced back to a pure stream of hydrogen gas (up to 1000 bar).

Our H2 Electrochemical Pump research focuses on hydrogen purification from impure gas streams containing methane, carbon monoxide, carbon dioxide, other low-mw hydrocarbons, and hydrogen sulphide. These impurities would typically be present in hydrogen produced from steam methane reforming or in natural gas blending.

Poison mitigation strategies for the use of impure hydrogen in electrochemical hydrogen pumps and fuel cells - Jackson C, Raymakers L, Mulder M, Kucernak A, et al., J. Power Sources, 2020, 472, 228476.

• The Floating Electrode.

The floating electrode allows the evaluation of electrocatalysts for fuel cell and electrolyser reactions without the apparent mass-transport limitations of other methods such as the rotating disc electrode (RDE). This method typically examines ultra-low catalyst loadings (0.1-10 µgPt cm-2), and can identify electrochemical characteristics not visible via traditional techniques.

Electrocatalytic performance of fuel cell reactions at low catalyst loading and high mass transport - Zalitis CM, Kramer D, Kucernak AR, Phys. Chem. Chem. Phys., 2013, 15, 4329-4340.

• The Gas Accessible Membrane Electrode (GAME).

The GAME is a complete electrode configuration providing a well-defined three-phase interface designed to facilitate rapid, two-way, mass transport – similarly, with a rate constant 1-2 orders of magnitude larger than other techniques. Due to the system design, the electrochemical data can be complemented further with coupled, on-line and in situ analyses (such as mass spectrometry, infrared spectroscopy, etc.), lending itself to studying complex electrochemical conversion process such as carbon dioxide reduction.

Gas Accessible Membrane Electrode (GAME): A Versatile Platform for Elucidating Electrocatalytic Processes Using Real-Time and in Situ Hyphenated Electrochemical Techniques – Zhang G, Kucernak A, ACS Catal., 2020, 10 (17), 9684–9693.

One of the biggest challenges facing the wide-scale deployment of PEMFCs is considered to be the requirement for precious metal catalysts. Traditionally, platinum (and alloys thereof) are used on both sides of the cell (HOR and ORR reactions). While one research aim is to optimise these catalysts, thereby reducing the quantity needed per cell, another is to remove this reliance entirely.

For the Oxygen Reduction Reaction (ORR): single atom, non-precious group metal catalysts (NPGMs) are one of the most promising catalyst candidates to date. These generally take the form of pyrolysed transition metal complexes supported on carbon materials, M-Nx/C.

Recent work has explored the use of Fe-N/C materials identifying particularly high performance in single atomic catalysts synthesised by the exchange of iron into a preformed carbon-nitrogen matrix. These materials have a high density of these atomic active sites (7 wt%Fe vs. the typical 1-3 wt%Fe) and display excellent ORR activity in both RDE and device testing.

High loading of single atomic iron sites in Fe–NC oxygen reduction catalysts for proton exchange membrane fuel cells – Mehmood A, Gong M, Jaouen F, et al., Nat. Catal., 2022, 5, 311–323.

Besides Fe-N/Cs, other transition metals show promising performance, and we are also exploring the potential for NPGM catalysts in other applications.