In this section
@article{Bahou:2020:10.1021/acs.orglett.0c00935,
author = {Bahou, K and Braddock, D and Meyer, A and Savage, GP},
doi = {10.1021/acs.orglett.0c00935},
journal = {Organic Letters},
pages = {3176--3179},
title = {Relay cross metathesis for the iterative construction of terpenoids and synthesis of a diterpene benzoate macrolide of biogenetic relevance to the bromophycolides},
url = {http://dx.doi.org/10.1021/acs.orglett.0c00935},
volume = {22},
year = {2020}
}
TY - JOUR
AB - We report a relay cross metathesis (ReXM) reaction for the construction of terpenoids in an iterative protocol. The protocol features the cross metathesis of a relay-actuated Δ6,7-functionalized C10-monoterpenoid alcohol with C10-monoterpenoid citral to form a C15-sesquiterpene. Subsequent functional group manipulation allows for the method to be repeated in an iterative fashion. The method is used for the synthesis of a diterpene-benzoate macrolide of biogenetic relevance to the bromophycolide family of natural products.
AU - Bahou,K
AU - Braddock,D
AU - Meyer,A
AU - Savage,GP
DO - 10.1021/acs.orglett.0c00935
EP - 3179
PY - 2020///
SN - 1523-7052
SP - 3176
TI - Relay cross metathesis for the iterative construction of terpenoids and synthesis of a diterpene benzoate macrolide of biogenetic relevance to the bromophycolides
T2 - Organic Letters
UR - http://dx.doi.org/10.1021/acs.orglett.0c00935
UR - http://hdl.handle.net/10044/1/79037
VL - 22
ER -