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@article{Young:2020:10.1007/s11244-019-01210-0,
author = {Young, CT and von, Goetze R and Tomov, AK and Zaccaria, F and Britovsek, GJP},
doi = {10.1007/s11244-019-01210-0},
journal = {Topics in Catalysis},
pages = {294--318},
title = {The mathematics of ethylene oligomerisation and polymerisation},
url = {http://dx.doi.org/10.1007/s11244-019-01210-0},
volume = {63},
year = {2020}
}

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TY  - JOUR
AB  - Linear α-olefins or LAOs are produced by the catalytic oligomerisation of ethylene on a multimillion ton scale annually. A range of LAOs is typically obtained with varying chain lengths which follow a distribution. Depending on the catalyst, various types of distributions have been identified, such as Schulz–Flory, Poisson, alternating and selective oligomerisations such as ethylene trimerisation to 1-hexene and tetramerisation to 1-octene. A comprehensive mathematical analysis for all oligomer distributions is presented, showing the relations between the various distributions and with ethylene polymerisation, as well as providing mechanistic insight into the underlying chemical processes.Linear α-olefins or LAOs are produced by the catalytic oligomerisation of ethylene on a multimillion ton scale annually. A range of LAOs is typically obtained with varying chain lengths which follow a distribution. Depending on the catalyst, various types of distributions have been identified, such as Schulz–Flory, Poisson, alternating and selective oligomerisations such as ethylene trimerisation to 1-hexene and tetramerisation to 1-octene. A comprehensive mathematical analysis for all oligomer distributions is presented, showing the relations between the various distributions and with ethylene polymerisation, as well as providing mechanistic insight into the underlying chemical processes.
AU  - Young,CT
AU  - von,Goetze R
AU  - Tomov,AK
AU  - Zaccaria,F
AU  - Britovsek,GJP
DO  - 10.1007/s11244-019-01210-0
EP  - 318
PY  - 2020///
SN  - 1022-5528
SP  - 294
TI  - The mathematics of ethylene oligomerisation and polymerisation
T2  - Topics in Catalysis
UR  - http://dx.doi.org/10.1007/s11244-019-01210-0
UR  - https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000515805600002&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=a2bf6146997ec60c407a63945d4e92bb
UR  - https://link.springer.com/article/10.1007/s11244-019-01210-0
UR  - http://hdl.handle.net/10044/1/101270
VL  - 63
ER  -

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