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@article{Ho:2023:10.1002/cptc.202200290,
author = {Ho, SKY and Ezeorah, C and Chari, S and SalehiReyhani, A and Britovsek, GJP},
doi = {10.1002/cptc.202200290},
journal = {ChemPhotoChem},
pages = {1--6},
title = {Monitoring lightdriven oxygen insertion reactions into metal carbon bonds by LEDNMR spectroscopy},
url = {http://dx.doi.org/10.1002/cptc.202200290},
volume = {7},
year = {2023}
}

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TY  - JOUR
AB  - The facile light-driven insertion reaction of oxygen into metal carbon bonds of the BPI (1,3-bis(2-pyridylimino)isoindole) complexes [Pt(BPI)Me] and [Pd(BPI)Me] has been investigated by LED-NMR in CDCl3. The initial insertion reaction leads to peroxo complexes [Pt(BPI)OOMe] and [Pd(BPI)OOMe], which undergo further reactions over time. Spectra were recorded at 1 minute time intervals, which enabled the tracking of the methyl substituent, which eventually generates formaldehyde (and methanediol) and methanol in almost equal proportions. Degradation of the solvent CDCl3 to phosgene and DCl in the presence of oxygen and light leads to several side reactions. DCl reacts with [M(BPI)Me] and [M(BPI)OOMe] to form [M(BPI)Cl], whereas phosgene reacts with insitu generated methanol to chloro methylformate and dimethyl carbonate.
AU  - Ho,SKY
AU  - Ezeorah,C
AU  - Chari,S
AU  - SalehiReyhani,A
AU  - Britovsek,GJP
DO  - 10.1002/cptc.202200290
EP  - 6
PY  - 2023///
SN  - 2367-0932
SP  - 1
TI  - Monitoring lightdriven oxygen insertion reactions into metal carbon bonds by LEDNMR spectroscopy
T2  - ChemPhotoChem
UR  - http://dx.doi.org/10.1002/cptc.202200290
UR  - https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cptc.202200290
UR  - http://hdl.handle.net/10044/1/104309
VL  - 7
ER  -

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