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@article{Martinez-Ferrate:2016:10.1039/c5dt04358a,
author = {Martinez-Ferrate, O and Lopez-Valbuena, JM and Martinez, Belmonte M and White, AJP and Benet-Buchholz, J and Britovsek, GJP and Claver, C and van, Leeuwen PWNM},
doi = {10.1039/c5dt04358a},
journal = {Dalton Transactions},
pages = {3564--3576},
title = {Novel iminopyridine derivatives: ligands for preparation of Fe(II) and Cu(II) dinuclear complexes},
url = {http://dx.doi.org/10.1039/c5dt04358a},
volume = {45},
year = {2016}
}

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TY  - JOUR
AB  - A series of imino- and amino-pyridine ligands based on dihydrobenzofurobenzofuran (BFBF) and methanodibenzodioxocine (DBDOC) backbones have been synthesized. These ligands form exclusively dinuclear complexes with metals such as iron(II) and copper(II). The structures for complexes 15, 16, 18, 19, 20, 21, 23, and 24 were determined by X-ray crystallography. The complexes show large distances for the metal nuclei and different geometries depending on the nature of the metal. An octahedral geometry was observed for the iron(II) complexes, while copper(II) complex 24 showed a distorted trigonal bipyramidal geometry. The iron(II) complexes showed activity as catalysts in the cycloaddition of CO2 to epoxides, obtaining moderate yields of cyclic carbonates.
AU  - Martinez-Ferrate,O
AU  - Lopez-Valbuena,JM
AU  - Martinez,Belmonte M
AU  - White,AJP
AU  - Benet-Buchholz,J
AU  - Britovsek,GJP
AU  - Claver,C
AU  - van,Leeuwen PWNM
DO  - 10.1039/c5dt04358a
EP  - 3576
PY  - 2016///
SN  - 1477-9226
SP  - 3564
TI  - Novel iminopyridine derivatives: ligands for preparation of Fe(II) and Cu(II) dinuclear complexes
T2  - Dalton Transactions
UR  - http://dx.doi.org/10.1039/c5dt04358a
VL  - 45
ER  -

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