@article{Bakewell:2015:10.1039/c5dt00192g,
author = {Bakewell, C and Fateh-Iravani, G and Beh, D and Myers, D and Tabthong, S and Hormnirun, P and White, AJ and Long, N and Williams, CK},
doi = {10.1039/c5dt00192g},
journal = {Dalton Transactions},
title = {Comparing a series of 8-quinolinolato complexes of aluminium, titanium and zinc as initiators for the ring-opening polymerization of rac-lactide.},
url = {http://dx.doi.org/10.1039/c5dt00192g},
volume = {44},
year = {2015}
}

Download

TY  - JOUR
AB  - The preparation and characterization of a series of 8-hydroxyquinoline ligands and their complexes with Ti(iv), Al(iii) and Zn(ii) centres is presented. The complexes are characterized using NMR spectroscopy, elemental analysis and, in some cases, by single crystal X-ray diffraction experiments. The complexes are compared as initiators for the ring-opening polymerization of racemic-lactide; all the complexes show moderate/good rates and high levels of polymerization control. In the case of the titanium or aluminium complexes, moderate iso-selectivity is observed (Pi = 0.75), whereas in the case of the zinc complexes, moderate hetero-selectivity is observed (Ps = 0.70).
AU  - Bakewell,C
AU  - Fateh-Iravani,G
AU  - Beh,D
AU  - Myers,D
AU  - Tabthong,S
AU  - Hormnirun,P
AU  - White,AJ
AU  - Long,N
AU  - Williams,CK
DO  - 10.1039/c5dt00192g
PY  - 2015///
SN  - 1477-9226
TI  - Comparing a series of 8-quinolinolato complexes of aluminium, titanium and zinc as initiators for the ring-opening polymerization of rac-lactide.
T2  - Dalton Transactions
UR  - http://dx.doi.org/10.1039/c5dt00192g
UR  - http://hdl.handle.net/10044/1/23444
VL  - 44
ER  - 

Download