@article{Nako:2015:10.1039/c5dt02144h, author = {Nako, AE and White, AJ and Crimmin, MR}, doi = {10.1039/c5dt02144h}, journal = {Dalton Transactions}, pages = {12530--12534}, title = {Bis(σ-B-H) complexes of copper(i): precursors to a heterogeneous amine-borane dehydrogenation catalyst}, url = {http://dx.doi.org/10.1039/c5dt02144h}, volume = {44}, year = {2015} }
TY - JOUR AB - A series of bis(σ-B-H) complexes of copper(i) have been prepared by displacement of arene solvent from a β-diketiminate copper(i) complex by four-coordinate boranes, H3B-L (L = NMe3, lutidine). In the presence of the same copper arene complex, the secondary amine-borane H3B-NMe2H undergoes dehydrogenation. We provide evidence for formation of a heterogengous catalyst from decomposition of the solution species. AU - Nako,AE AU - White,AJ AU - Crimmin,MR DO - 10.1039/c5dt02144h EP - 12534 PY - 2015/// SN - 1477-9226 SP - 12530 TI - Bis(σ-B-H) complexes of copper(i): precursors to a heterogeneous amine-borane dehydrogenation catalyst T2 - Dalton Transactions UR - http://dx.doi.org/10.1039/c5dt02144h UR - http://hdl.handle.net/10044/1/24644 VL - 44 ER -
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