In this section
@article{Malko:2016:10.1016/j.jpowsour.2016.05.035,
author = {Malko, D and lopes, T and Ticianelli, E and Kucernak, A},
doi = {10.1016/j.jpowsour.2016.05.035},
journal = {Journal of Power Sources},
pages = {189--200},
title = {A catalyst layer optimisation approach using electrochemical impedance spectroscopy for PEM fuel cells operated with pyrolysed transition metal-N-C catalysts},
url = {http://dx.doi.org/10.1016/j.jpowsour.2016.05.035},
volume = {323},
year = {2016}
}
TY - JOUR
AB - The effect of the ionomer to carbon (I/C) ratio on the performance of single cell polymer electrolyte fuel cells is investigated for three different types of non-precious metal cathodic catalysts. Polarisation curves as well as impedance spectra are recorded at different potentials in the presence of argon or oxygen at the cathode and hydrogen at the anode. It is found that a optimised ionomer content is a key factor for improving the performance of the catalyst. Non-optimal ionomer loading can be assessed by two different factors from the impedance spectra. Hence this observation could be used as a diagnostic element to determine the ideal ionomer content and distribution in newly developed catalyst-electrodes. An electrode morphology based on the presence of inhomogeneous resistance distribution within the porous structure is suggested to explain the observed phenomena. The back-pressure and relative humidity effect on this feature is also investigated and supports the above hypothesis. We give a simple flowchart to aid optimisation of electrodes with the minimum number of trials.
AU - Malko,D
AU - lopes,T
AU - Ticianelli,E
AU - Kucernak,A
DO - 10.1016/j.jpowsour.2016.05.035
EP - 200
PY - 2016///
SN - 0378-7753
SP - 189
TI - A catalyst layer optimisation approach using electrochemical impedance spectroscopy for PEM fuel cells operated with pyrolysed transition metal-N-C catalysts
T2 - Journal of Power Sources
UR - http://dx.doi.org/10.1016/j.jpowsour.2016.05.035
UR - http://hdl.handle.net/10044/1/32371
VL - 323
ER -
Prof. Anthony Kucernak
G22B
Molecular Sciences Research Hub (MSRH)
Imperial College London
White City Campus
London
W12 0BZ
United Kingdom
Phone: +44 (0)20 7594 5831
Fax: +44 (0)20 7594 5804
Email: anthony@imperial.ac.uk