@article{Malko:2017:10.1016/j.elecom.2017.09.004,
author = {Malko, D and Kucernak, ARJ},
doi = {10.1016/j.elecom.2017.09.004},
journal = {Electrochemistry Communications},
pages = {67--71},
title = {Kinetic isotope effect in the oxygen reduction reaction (ORR) over Fe-N/C catalysts under acidic and alkaline conditions.},
url = {http://dx.doi.org/10.1016/j.elecom.2017.09.004},
volume = {83},
year = {2017}
}

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TY  - JOUR
AB  - Heat treated Fe-N/C materials which are highly effective oxygen reduction catalysts in alkaline and acid, show a significant kinetic isotope effect (KIE). The values in acid (~3.4) and alkaline (~2.5) are much larger than the value for the metal free catalyst in acid (~1.8) suggesting that the rate determining step (RDS) is a proton coupled electron transfer in acid with a significant pathway involving a proton independent step under an alkaline environment
AU  - Malko,D
AU  - Kucernak,ARJ
DO  - 10.1016/j.elecom.2017.09.004
EP  - 71
PY  - 2017///
SN  - 1388-2481
SP  - 67
TI  - Kinetic isotope effect in the oxygen reduction reaction (ORR) over Fe-N/C catalysts under acidic and alkaline conditions.
T2  - Electrochemistry Communications
UR  - http://dx.doi.org/10.1016/j.elecom.2017.09.004
UR  - http://hdl.handle.net/10044/1/50616
VL  - 83
ER  - 

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