In this section
@article{Wilkinson:2019:10.1039/c8dt04215b,
author = {Wilkinson, L and Massey, E and Yue, T and White, A and Long, N},
doi = {10.1039/c8dt04215b},
journal = {Dalton Transactions},
pages = {72--78},
title = {Cyanoferrocenes as redox-active metalloligands for coordination-driven self-assembly},
url = {http://dx.doi.org/10.1039/c8dt04215b},
volume = {48},
year = {2019}
}
TY - JOUR
AB - Ferrocene-based Lewis bases have found utility as metalloligands in a wide variety of applications. The coordination chemistry of cyanoferrocenes however, is underexplored. Herein, we describe a new synthetic protocol for the generation of cyanoferrocenes. The coordination chemistry of these metalloligands to [Cu(NCMe)4][PF6], [(PPh3)2Cu(NCMe)2][PF6] and [(dppf)Cu(NCMe)2][PF6] salts has been explored, providing crystallographic evidence of cluster and polymeric forms of 1,1′- and 1,2-dicyanoferrocene complexes. The stability of the complexes and ligand dissociation were found to be strongly solvent-dependent.
AU - Wilkinson,L
AU - Massey,E
AU - Yue,T
AU - White,A
AU - Long,N
DO - 10.1039/c8dt04215b
EP - 78
PY - 2019///
SN - 1477-9234
SP - 72
TI - Cyanoferrocenes as redox-active metalloligands for coordination-driven self-assembly
T2 - Dalton Transactions
UR - http://dx.doi.org/10.1039/c8dt04215b
UR - http://hdl.handle.net/10044/1/66346
VL - 48
ER -
Professor Nick Long
Email: n.long@imperial.ac.uk
Telephone: +44 (0)20 7594 5781
501J
Molecular Sciences Research Hub
White City Campus
