In this section
@article{Miller:2019:10.1039/c9cc01496a,
author = {Miller, P and Apps, S and Long, N},
doi = {10.1039/c9cc01496a},
journal = {Chemical Communications},
pages = {6579--6582},
title = {Cobalt(-I) triphos dinitrogen complexes: activation and silyl-functionalisation of N2},
url = {http://dx.doi.org/10.1039/c9cc01496a},
volume = {55},
year = {2019}
}
TY - JOUR
AB - The cobalt dinitrogen complexes [{(EP3Ph)Co(μ-N2)}2Mg(THF)4], with triphos ligand scaffolds (EP3Ph, E = N or CMe), were prepared via two electron reductions of the Co(I) precursors [CoCl(EP3Ph)]. Both complexes showed high degrees of N2 activation owing to the formation of a rare M–NN–Mg–NN–M bridging-magnesium core. These systems showed further N2 functionalisation reactivity by silylation, forming silyldiazenido complexes [(EP3Ph)Co(NNSiMe3)].
AU - Miller,P
AU - Apps,S
AU - Long,N
DO - 10.1039/c9cc01496a
EP - 6582
PY - 2019///
SN - 1359-7345
SP - 6579
TI - Cobalt(-I) triphos dinitrogen complexes: activation and silyl-functionalisation of N2
T2 - Chemical Communications
UR - http://dx.doi.org/10.1039/c9cc01496a
UR - http://hdl.handle.net/10044/1/70515
VL - 55
ER -
Professor Nick Long
Email: n.long@imperial.ac.uk
Telephone: +44 (0)20 7594 5781
501J
Molecular Sciences Research Hub
White City Campus
