In this section
@article{Azzouzi:2020:10.1002/solr.201900581,
author = {Azzouzi, M and Calado, P and Telford, A and Eisner, F and Hou, X and Kirchartz, T and Barnes, P and Nelson, J},
doi = {10.1002/solr.201900581},
journal = {Solar Rrl},
title = {Overcoming the limitations of transient photovoltage measurements for studying recombination in organic solar cells},
url = {http://dx.doi.org/10.1002/solr.201900581},
volume = {4},
year = {2020}
}
TY - JOUR
AB - Transient photovoltage (TPV) measurements are frequently used to study recombination processes in thin-film solar cells by probing the decay of a small optically-induced voltage perturbation to infer the charge carrier dynamics of devices at open circuit. However, the validity of this method to probe organic semiconductors has recently come into doubt due to large discrepancies in reported carrier lifetime values for the same systems, and the reporting of unrealistic reaction order values. In this work, we explore the validity of TPV to extract reliable charge carrier lifetimes in thin-film solar cells through the use of time-dependent drift diffusion simulations and measurements. We find that in low mobility materials, TPV serves primarily as a probe of charge carrier redistribution in the bulk rather than bulk recombination dynamics, and that the extracted time constant is highly mobility dependent. To address this shortcoming, we develop Transient Photo-Charge (TPQ) a new technique to measure the charge carrier density during the photo-voltage decay and apply it to study the recombination dynamics in a series of (fullerene and non-fullerene) organic solar cell systems. We show that using this technique the charge carrier recombination lifetime in the active layer can be more accurately determined.
AU - Azzouzi,M
AU - Calado,P
AU - Telford,A
AU - Eisner,F
AU - Hou,X
AU - Kirchartz,T
AU - Barnes,P
AU - Nelson,J
DO - 10.1002/solr.201900581
PY - 2020///
SN - 2367-198X
TI - Overcoming the limitations of transient photovoltage measurements for studying recombination in organic solar cells
T2 - Solar Rrl
UR - http://dx.doi.org/10.1002/solr.201900581
UR - http://hdl.handle.net/10044/1/78598
VL - 4
ER -
Jenny Nelson
Professor of Physics
1007, Huxley Building
South Kensington, London, SW7 2AZ