BibTex format
@article{Coker:2024:10.1073/pnas.2403879121,
author = {Coker, JF and Moro, S and Gertsen, AS and Shi, X and Pearce, D and van, der Schelling MP and Xu, Y and Zhang, W and Andreasen, JW and Snyder, CR and Richter, LJ and Bird, MJ and McCulloch, I and Costantini, G and Frost, JM and Nelson, J},
doi = {10.1073/pnas.2403879121},
journal = {Proc Natl Acad Sci U S A},
title = {Perpendicular crossing chains enable high mobility in a noncrystalline conjugated polymer.},
url = {http://dx.doi.org/10.1073/pnas.2403879121},
volume = {121},
year = {2024}
}
RIS format (EndNote, RefMan)
TY - JOUR
AB - The nature of interchain π-system contacts, and their relationship to hole transport, are elucidated for the high-mobility, noncrystalline conjugated polymer C16-IDTBT by the application of scanning tunneling microscopy, molecular dynamics, and quantum chemical calculations. The microstructure is shown to favor an unusual packing motif in which paired chains cross-over one another at near-perpendicular angles. By linking to mesoscale microstructural features, revealed by coarse-grained molecular dynamics and previous studies, and performing simulations of charge transport, it is demonstrated that the high mobility of C16-IDTBT can be explained by the promotion of a highly interconnected transport network, stemming from the adoption of perpendicular contacts at the nanoscale, in combination with fast intrachain transport.
AU - Coker,JF
AU - Moro,S
AU - Gertsen,AS
AU - Shi,X
AU - Pearce,D
AU - van,der Schelling MP
AU - Xu,Y
AU - Zhang,W
AU - Andreasen,JW
AU - Snyder,CR
AU - Richter,LJ
AU - Bird,MJ
AU - McCulloch,I
AU - Costantini,G
AU - Frost,JM
AU - Nelson,J
DO - 10.1073/pnas.2403879121
PY - 2024///
TI - Perpendicular crossing chains enable high mobility in a noncrystalline conjugated polymer.
T2 - Proc Natl Acad Sci U S A
UR - http://dx.doi.org/10.1073/pnas.2403879121
UR - https://www.ncbi.nlm.nih.gov/pubmed/39226361
VL - 121
ER -